4-Hydroxy-2,2,6,6-tetramethylpiperidinium chloride–hydroxonium chloride (3/1)
نویسندگان
چکیده
The crystal structure of the title compound, C(9)H(20)NO(+)·Cl(-)·0.33(H(3)O(+)·Cl(-)), is composed of 4-hydr-oxy-2,2,6,6-tetra-methyl-piperidinium cations, hydroxonium cations and chloride anions, which are connected via O-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonding. The 4-hydr-oxy-2,2,6,6-tetra-methyl-piperidinium cation and one of the two crystallographically independent chloride anions are located on a mirror plane. The hydroxonium cation is located on a threefold axis and the second crystallographically independent chloride anion is located on a sixfold rotoinversion axis. Due to symmetry, the hydroxonium cation is disordered over two positions.
منابع مشابه
4-Hydroxy-2,2,6,6-tetramethylpiperidinium perchlorate
In the title salt, C(9)H(20)NO(+)·ClO(4) (-), inter-molecular hydrogen bonds are observed, which determine the crystal packing.
متن کامل4-Hydroxy-2,2,6,6-tetramethylpiperidinium hydrogensulfate monohydrate
In the title compound, C(9)H(20)NO(+)·HO(4)S(-)·H(2)O, the piperi-dinium ring adopts a chair conformation. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds form an extensive three-dimensional network, which consolidates the crystal structure.
متن کامل4-Hydroxy-2,2,6,6-tetramethylpiperidinium trichloroacetate
In the crystal structure of the title compound, C(9)H(20)NO(+)·Cl(3)CCOO(-), the cations and anions are connected via O-H⋯O, N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonding. The six-membered ring adopts a chair conformation with the hydroxyl group in an equatorial position.
متن کامل2,2,6,6-Tetramethylpiperidinium triisopropoxysilanethiolate
The crystal of the title compound, C(9)H(20)N(+)·C(9)H(21)O(3)SSi(-), is built of aggregates, each made up of two 2,2,6,6-tetra-methyl-piperidinium cations and two triisopropoxysilanethiol-ate anions. The aggregates are linked by four N-H⋯S bonds and correspond to an R(2) (4)(8) graph-set motif.
متن کامل4-Hydroxy-2,2,6,6-tetramethylpiperidinium trifluoroacetate
The title compound, C(9)H(20)NO(+)·C(2)F(3)O(2) (-), is an important inter-mediate in the synthesis of hindered light stabilizers. The piperidinium ring adopts a chair conformation with the hydroxyl group in an equatorial position. The crystal packing is stabilized by O-H⋯O and N-H⋯O hydrogen bonds. The CF(3) group is disordered over two positions with almost equal site occupancy factors.
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